Excellent toluene removal via adsorption by honeycomb adsorbents under high temperature and humidity conditions

Article information

Environmental Engineering Research. 2020;25(2):171-177
Publication date (electronic) : 2019 March 19
doi : https://doi.org/10.4491/eer.2018.444
1enbion Inc., Daejeon 34026, Republic of Korea
2Korea Institute of Energy Research, Daejeon 34129, Republic of Korea
Corresponding author: Email: yim@enbion.co.kr, Tel: +82-42-863-8675, Fax: +82-42-863-8677
Received 2018 December 21; Accepted 2019 March 1.

Abstract

Removal through adsorption is the most widely used and effective treatment method for volatile organic compounds (VOCs) in exhaust gases. However, at high temperatures and humidity, adsorption is competitive due to the presence of moisture and unsmooth physical adsorption thereby deteriorating adsorption performance. Therefore, water adsorption honeycomb (WAH) and VOCs adsorption honeycomb (VAH) were prepared to improve VOCs adsorption at high temperatures and humidity. Adsorbed toluene amounts on single honeycomb (SH), containing only VAH, and combined honeycomb (CH), containing WAH and VAH, were determined. Further, the toluene adsorption rates of honeycomb adsorbents mounted on rotary systems, VAH-single rotor (SR) and WAH/VAH-dual rotor (DR) were determined. Toluene adsorption by WAH/VAH-CH (inlet temperature: 40–50°C; absolute humidity: 28–83 gH2O/kg-dry air) was 1.6 times that by VAH-SH, and the water adsorption efficiency of WAH/VAH-CH was 1.7 times that of VAH-SH. The adsorption/removal efficiency of the WAH/VAH-DR (inlet temperature: 45°C; absolute humidity: 37.5 gH2O/kg-dry air) was 3% higher than that of VAH-SR. This indicates that the WAH at the rotor inlet selectively removed water, thereby improving the adsorption efficiency of the VAH at the outlet.

1. Introduction

Various volatile organic compounds (VOCs) are emitted during the manufacture and storage of organic solvents, paints, coating materials, and petrochemical products [1]. These compounds are harmful for human health and combine with nitrogen oxides in the atmosphere, causing secondary air pollution such as photochemical smog [2]. Emissions of VOCs are becoming a global concern, and many countries are making great efforts to reduce them.

Treatment methods for VOCs can be broadly divided into collection and removal processes [3]. Regeneration processes include distillation, adsorption, and absorption, while thermal incineration, catalytic incineration, and catalytic oxidation are used for the removal of VOCs. Adsorption is advantageous for energy saving as it allows collection or recycling of organic solvents generated in industrial processes [3, 4].

The use of an adsorption tower filled with granular adsorbents is a typical adsorption method [5]. However, large pressure losses occur in fixed adsorption towers filled with granular adsorbents, and therefore a separate pressurizing device is required to process exhaust gases [6]. In recent years, rotary adsorption systems that can adsorb and regenerate VOCs while reducing pressure load through the use of a honeycomb-like structure coated with adsorbent materials has been widely applied, and studies on such systems are being actively conducted [79]. Such adsorption systems have a simple configuration and minimize installation scale as they require only one adsorption rotor, which can be used for several adsorption and regeneration cycles [10, 11].

The adsorption performance of an adsorbent depends on its structure, type, and composition. Activated carbon and zeolite are the most widely used adsorbents [12, 13]. In recent years, zeolite has become more popular than activated carbon due to its high regeneration ability. Zeolite can be either hydrophilic or hydrophobic depending on its silica and alumina molar ratios. Hydrophobic zeolite can be used under high moisture conditions, as it will selectively adsorb the target compound while repelling water [1416]. However, the ratio of high and low silica zeolite needs to be optimized to adsorption conditions because high humidity deteriorates its absorptivity. Further, zeolite is sensitive to moisture present in the atmosphere and temperature [12, 17]. The effects on adsorption by differences in physicochemical properties between the adsorbent and the adsorbate and the competitive adsorption of between moisture and VOCs had been reported [14, 18]. Moreover, it is difficult to remove VOCs under high temperature and humidity conditions. In order to solve these problems, we developed a rotor system with a dual adsorption system for removing simultaneously VOCs under high temperature and humidity conditions.

In this study, a water adsorption honeycomb (WAH) and VOC adsorption honeycomb (VAH) were prepared. Further, a single honeycomb (SH) composed of only VAH and a combined honeycomb (CH) with both WAH and VAH were fabricated. A VAH-single rotor (SR) and WAH/VAH-DR, which were mounted on a rotary system, were developed. Subsequently, the VAH-SH and WAH/VAH-CH were attached to a continuous adsorption/desorption device. The amount of toluene adsorbed was then evaluated under varying inlet temperatures and absolute humidity. Finally, the toluene removal efficiencies of VAH-SR and WAH/VAH-DR were compared under high temperature and humidity conditions.

2. Experimental Methods

2.1. Preparation of Adsorption Honeycomb

Fine silica powder (SS-230, Particle Size: 3.5 μm, Schemtech) was used for the fabrication of the WAH. This powder was dispersed in a 3% solution of silica sol (YGS-30, Young Il Chemical), which is an inorganic binder. A glass fiber honeycomb was dipped in this mixture, dried at 100°C for 12 h, and then calcined at 300°C for 2 h to prepare the WAH. ZSM-5 zeolite (SiO2/Al2O3 molar ratio > 100, UOP) powder was used as the adsorbent for the VAH. A ceramic honeycomb was dipped in a 10% silica sol solution containing dispersed zeolite, dried at 100°C for 12 h, and then calcined at 500°C for 6 h to prepare the VAH.

The fabricated WAH and VAH was cut cylinders measuring 100 mm in diameter, 100 and 300 mm in length to prepare the WAH-SH and VAH-SH, respectively. The fabricated WAH and VAH were combined in a length ratio of 1:3 (v/v) at the adsorption honeycomb and then cut into cylinders measuring 100 mm in diameter and 400 mm in total length to prepare the WAH/VAH-CH. Further, WAH-SR and VAH-SR with dimensions of 500 mm (diameter), 200 and 400 mm (length) was used to confirm the adsorption/removal efficiency. The WAH/VAH-DR, measuring 500 mm in diameter and 600 mm in total length, was fabricated by combining the desiccant and adsorbent in a ratio of 1:2 (v/v).

2.2. Fixed Bed Continuous Adsorption/Desorption Device

Adsorption experiments with the VAH-SH and WAH/VAH-CH were carried out using a fixed-bed continuous adsorption/desorption device as shown in Fig. 1. The experimental apparatus consisted of an adsorbate generation module, adsorbent filling module, and analysis module. Toluene was injected into the adsorbent generation module at a constant concentration of 100 ppm using a mass flow controller. Further, a blower was used to maintain the gas hourly space velocity (GHSV) at 20,000 /h. The absolute humidity was maintained at 28–83 gH2O/kg-dry air using an aluminum heating block (250 × 200 × 20 mm, 3 kW, Solution Eng.) and a liquid pump (HPLH PF 200, CAT, Germany) depending on the required experimental conditions. In the adsorbent filling module, VAH-SH and WAH/VAH-CH (diameter: 100 mm; length: 400 mm) were filled inside a stainless-steel cylindrical reactor with an inner diameter of 105 mm and a length of 410 mm. Subsequently, the amounts of water and toluene adsorbed were confirmed. During adsorption, No. 2, 3, 5, 6, 8, and 9 valves were opened, and the inlet temperature was kept constant. During desorption, No. 1, 4, 8, and 6 valves were opened and a constant temperature was maintained.

Fig. 1

Schematic diagram of the sequential reactor used for adsorption/desorption. VAH-SH and WAH/VAH-CH were filled inside the adsorbent filling module.

The temperature and humidity in the inlet and outlet of adsorber were measured using a temperature/humidity sensor (SK-L200TH, SATO, Japan). Toluene concentration was determined using a total hydrocarbon analyzer (51i, Thermo, USA) equipped with a flame ionization detector.

To calculate the saturated adsorption capacity of the adsorbent, amount of adsorbate per unit adsorbent, and breakthrough adsorption time, toluene and air containing moisture were injected into the reactor at a constant concentration. Toluene concentration was measured by considering that adsorption equilibrium was attained when the toluene concentration at the outlet of the adsorber before and after adsorption was almost equal to the toluene concentration at the inlet.

The breakthrough curve is expressed as the ratio (C0/Ci) of outflow concentration (C0) to inflow concentration (Ci) according to the adsorption time (t). The outflow concentration is measured at the outlet of the adsorption reactor with respect to time. The adsorption amount refers to the saturated adsorbate amount adsorbed and can be calculated using Eq. (1) [13].

(1) q=1WCiQ(tT-1Ci0tCodt)

where q is the equilibrium adsorption amount (mg/g), Ci is the adsorbate concentration (ppm) at the inlet of the adsorption layer, Co is ppm at the outlet of the adsorption layer, W is the adsorbent filling amount (g), Q is the inflow rate (L/min) of the adsorbate gas, and tT is the time (min) at which the adsorbent reaches saturation.

2.3. Rotary Adsorption System

After determining the saturated adsorption capacities of VAH-SH and WAH/VAH-CH, a rotary system was introduced to fabricate the VAH-SR and WAH/VAH-DR. VAH-SR and WAH/VAH-DR were mounted on a rotary adsorption system, as shown in Fig. 2, and the corresponding VOC removal efficiencies of the rotary concentrator adsorption systems were evaluated. As shown in Fig. 2, the honeycomb rotor was divided into adsorption, desorption, and cooling zones (8:1:1 ratio) by the external equipment. The adsorption/removal rate of the honeycomb rotor (rotating at 3 RPH (revolutions per hour)) was measured. The zone in which complete adsorption was achieved at room temperature (about 20°C) was transferred to the desorption zone, so that the adsorbed adsorbate can be desorbed and regenerated by the regeneration air, which is maintained at 220°C. The desorption zone was moved to the cooling zone, where the temperature was reduced to 50°C (or lower) by some outside air entering the adsorption region so as to facilitate VOCs adsorption. Sequentially, the VOCs in the incoming gas were removed via adsorption on the regenerated honeycomb adsorbent. Toluene removal efficiency can be calculated using Eq. (2).

Fig. 2

Schematic diagram of the rotary honeycomb adsorption system (a: VAH-SR, b: WAH/VAH-DR) used for VOC removal.

(2) Removalefficiency(%)=(1-TolueneconcentrationafteradsorptionTolueneconcentrationbeforeadsorption)×100

2.4. Characterization of the Honeycomb Adsorbents

The shape, size, and distribution of particles on the surface of the WAH and VAH, fabricated in this study, were analyzed via scanning electron microscopy (SEM, TESCAN, Mira 3 LMV FEG, Czech). To determine the pore characteristics of the adsorbent, Brunauer-Emmett-Teller (BET) specific surface area (SBET), total pore volume (VT), and average pore diameter (Dp) were measured using a BET surface area analyzer (Micromeritics, ASAP2010, USA).

3. Results and Discussion

3.1. Physical Properties of Adsorbent

Fig. 3 shows the SEM images of WAH-SH (Fig. 3(a-1), (a-2)) containing fine silica powder and VAH-SH (Fig. 3(b-1), (b-2)) containing zeolite. SEM images of the surface of the WAH-SH, which is coated with fine silica powder, showed a uniform distribution of fine microcrystalline silica powder on the glass fiber surface (Fig. 3(a-2)). SEM images (VAH-SH) of the ceramic sheet surface coated with zeolite, ceramic fibers formed a grain-like structure and zeolite particles were uniformly distributed (Fig. 3(b-2)). Table 1 shows the surface area, pore volume, and Dp of fine silica powder and zeolite used as adsorbent materials, and zeolite-coated honeycomb adsorbent. The SBET of the fine silica powder (287.6 m2/g) was smaller than that of the ZSM-5 zeolite (410 m2/g) by 122.4 m2/g. However, VT (total pore volume) of fine silica powder was 7 times greater than that of the ZSM-5 zeolite powder, while its Dp was about 5.5 times larger than that of ZSM-5 zeolite. This may be attributable to the pores formed by the aggregation of non-crystalline fine silica particles. In addition, the specific surface area of the ZSM-5 zeolite powder was significantly reduced from 410 m2/g prior to coating to 152 m2/g after coating on the ceramic honeycomb. Some of the silica sol particles used as binder during coating may have been dispersed into the zeolite pores, thereby decreasing the surface area.

Fig. 3

SEM images of WAH-SH (a1, a2) as fine silica powder-coated honeycomb adsorbent and VAH-SH (b1, b2) as zeolite-coated honeycomb adsorbent.

Physical Properties of ZSM-5, Fine Silica Powder, ZSM-5 Coated Honeycomb, and Silica-Coated Glass Fiber Honeycomb

3.2. Water Adsorption Amount

To estimate the influence of relative humidity on the water adsorption capacity of WAH-SH, the absolute humidity (relative humidity) was set at 12.9 gH2O/kg-dry air (15%) and 49.1 gH2O/kg-dry air (60%). Water was continuously adsorbed at an inlet temperature of 50°C and a gas flow rate of 1 NCMM (normal cubic meter per min). The water absorption amounts calculated using Eq. (3) is shown in Table 2.

Water Adsorption Amount as a Function of Relative Humidity

(3) Wateradsorptionamount=(Adsorptionweightafteradsorption-Adsorptionweightbeforeadsorption)Adsorptionweightbeforeadsorption

The water adsorption amount by WAH-SH at absolute humidity (relative humidity) of 12.9 gH2O/kg-dry air (15%) and 49.1 gH2O/kg-dry air (60%) was 20 mg/g and 118 mg/g, respectively. Yang et al. [19] reported that silica has excellent water adsorption performance, and that its water adsorption capacity increases proportionally with increase in relative humidity. Therefore, WAH is considered to have a sufficiently high water adsorption capacity at the absolute humidity levels considered in this study.

3.3. Toluene Adsorption Amount

Fig. 4(a) shows the toluene adsorption capacity of VAH-SH as a function of temperature. Input gas temperatures of 40, 50, and 60°C, absolute humidity of 28.5 gH2O/kg-dry air, initial toluene concentration of 100 ppm, and GHSV of 20,000 /h were considered in this study. Adsorption was carried out continuously to measure the toluene adsorption amount. Toluene adsorption amounts were 28.66, 23.36, and 21.37 mg/g at input gas temperatures of 40, 50, and 60°C, respectively. Absorption efficiency decreased with increase in temperature because the absorptivity of an adsorbent is inversely proportional to temperature as physical adsorption involves Van der Waals interactions [20].

Fig. 4

a) Toluene adsorption amount as a function of input gas temperature (toluene concentration: 100 ppm; absolute humidity: 28.5 gH2O/kg-dry air; GHSV: 20,000/h; input gas temperature: 40, 50, and 60°C). b) Toluene adsorption amount as a function of input gas absolute humidity (toluene concentration: 100 ppm; absolute humidity: 28.5 and 49.1 gH2O/kg-dry air; GHSV: 20,000/h; input gas temperature: 50°C).

The influence of absolute humidity on toluene adsorption amount by VAH-SH was determined. Absolute humidity of 28.5 and 49.1 gH2O/kg-dry air, inlet temperature of 50°C, toluene concentration of 100 ppm, and GHSV of 20,000 /h were used for this purpose. Subsequently, continuous toluene adsorption was carried out, the results of which are shown in Fig. 4(b). At absolute humidity of 28.5 and 49.1 gH2O/kg-dry air, toluene adsorption amounts were 23.36 and 21.43 mg/g, respectively. A mixture of two or more types of substances (such as a mixture of toluene and water) causes competitive adsorption by VAH-SH. The moisture present in mixtures with high humidity may have diffused into the pores of VAH, thereby decreasing its toluene adsorption capacity. Therefore, under conditions above 49.1 gH2O/kg-dry air (60% RH) absolute humidity, toluene adsorption performance of the adsorbent would be decreased [21].

Based on the abovementioned results, adsorption experiments were carried out under high temperature and humidity conditions at an input gas temperature of 50°C and absolute humidity of 49.1 gH2O/kg-dry air. Subsequently, desorption was carried out five times at a temperature of 200°C and desorption gas flow rate of 0.2 NCMM to determine the durability of VAH. The average toluene adsorption amount was 20.53 ± 0.18 mg/g. The adsorption performance of the adsorbent was maintained without inactivation even after five cycles of toluene adsorption/desorption.

3.4. Comparison of the SH and CH Adsorbents

The adsorption performance of WAH/VAH-CH (adsorbent:desiccant ratio of 3:1) was evaluated at an input gas temperature of 50°C, absolute humidity (relative humidity) of 49.1 gH2O/kg-dry air (60%), and toluene concentration of 100 ppm (Fig. 5(a)). The adsorption amount refers to the saturated adsorbate amount adsorbed and can be calculated using Eq. (1). Toluene adsorption amount by VAH-SH was 21.34 mg/g, while that by WAH/VAH-CH was 34.29 mg/g, of which toluene adsorption by WAH was 0.45 mg/g. Toluene gas with high moisture contents may have passed through the WAH/VAH-CH, and the moisture may have been primarily adsorbed by the WAH, thereby lowering the moisture content of the gas. Thus, the selectivity of VAH for toluene was improved, and the toluene adsorption amount by WAH/VAH-CH was above 12.5 mg/g more than VAH-SH [21].

Fig. 5

a) Comparison of the adsorption curves of the single and combined absorbent systems. (toluene concentration: 100 ppm; GHSV: 20,000 /h; absolute humidity: 49.1 gH2O/kg-dry air; input gas temperature: 50°C). b) Comparison of the desorption curves of the single and combined absorbent systems. (inlet temperature: 200°C; gas flow rate: 0.2 NCMM).

Fig. 5(b) shows the desorption of adsorbate from WAH/VAH-CH and VAH-SH at an inlet temperature of 200°C and gas flow rate of 0.2 NCMM. Desorption from WAH/VAH-CH began at 5 min, and maximum toluene desorption (2,700 ppm) was achieved within 10 min. In the case of VAH-SH, desorption began at 8 min, the concentration of toluene desorbed after 11 min was 1,200 ppm, and tailing of the desorption curve was observed. The water adsorption amount by VAH-SH was higher than that by WAH/VAH-CH. This is because in the case of VAH-SH, desorption energy was used to desorb water besides toluene, thereby increasing desorption time [21].

3.5. Evaluation of Water and Toluene Adsorption using the Honeycomb Rotor System

Table 3 shows the water adsorption amount and toluene removal efficiency of the VAH-SR and WAH/VAH-DR. The water contents at the inlet and outlet of the honeycomb rotor system maintained at a temperature of 40°C and an absolute humidity (relative humidity) of 36 gH2O/kg-dry air (80%) were measured to determine water adsorption amount. The moisture content at the inlet of VAH-SR was 40.8 gH2O/kg-dry air, while that at its outlet was 34.5 gH2O/kg-dry air, which is a decrease in moisture content of approximately 6.3 gH2O/kg-dry air. At the outlet of the WAH/VAH-DR, water content was 29.8 gH2O/kg-dry air, which is less than that at its inlet by about 11.0 gH2O/kg-dry air. This indicates that the water removal capacity of WAH/VAH–DR is approximately 1.7 times that of VAH-SR. Water adsorption amount was determined as a function of the total honeycomb volume. It was observed that water adsorption amount per unit volume of VAH-SR was 80.7 g/m3, while that per unit volume of WAH/VAH-DR was 93.0 g/m3. This means that amount of water adsorbed per unit volume of WAH/VAH-DR is 1.15 times that per unit volume of VAH-SR. This is because the WAH present at the inlet may have adsorbed relatively more water.

Water Adsorption Amount and Toluene Removal Efficiency of the Single and Dual Honeycomb Rotor System

For evaluation of the toluene removal efficiency, the desorption flow rate was set at 2 and 3 NCMM. Conditions were temperature of 45°C, absolute humidity (relative humidity) of 37.5 gH2O/kg-dry air (60), toluene concentration of 100 ppm, and adsorption gas flow rate of 20 NCMM. The toluene adsorption efficiency of both types of rotors decreased with increase in number concentration. However, the decrease in the adsorption efficiency of the DR was smaller than that of the SR. Thus, the high toluene removal rate of the DR system may be attributable to the adsorption of water by the WAH present at the inlet of the DR system [21].

4. Conclusions

In this study, WAH/VAH-CH was prepared and evaluated on a fixed bed continuous adsorption/desorption system. WAH/VAH-DR was used for the evaluation by mounting WAH/VAH-CH on a rotary system. Toluene adsorption efficiencies were evaluated at high temperature and humidity conditions (inlet temperature of 40–50°C and absolute humidity of 28–83 gH2O/kg-dry air). The toluene adsorption amount decreased with increase in temperature and humidity. It was difficult to achieve high absorptivity with only VAH under high temperature and humidity conditions due to decreased Van der Waals interactions caused by increased temperature and competitive adsorption of two or more types of substances. WAH/VAH-CH and WAH/VAH-DR, which are composed of two adsorbent layers, were produced to improve VOC adsorption performance under high temperature and humidity conditions. Toluene and water adsorption amount by WAH/VAH-CH were 1.6 and 1.7 times, respectively, those of VAH-SH. Further, the toluene removal efficiency of WAH/VAH-DR was 3% higher than that of VAH-SR. The WAH at the rotor inlet may have primarily and selectively adsorbed water, thereby improving the adsorption performance of the VAH located at the rotor outlet. However, we have not identified the adsorption tendency and efficiency of the various VOCs in this study. Therefore, further studies for improving the efficiency of dehumidification and VOCs adsorption using the dual rotary adsorption system under various conditions (e.g., number of revolutions, types and concentrations of VOCs, composition ratio of desiccant and VOCs adsorbent, etc.) would be performed. It seems likely that the dual rotary adsorption system suggested by this study suitable for the air pollution control technology for a variety of VOCs emissions sources, if the results of this study are successful to design by determining the suitable operation conditions.

Acknowledgments

This subject is supported by Korea Ministry of Environment (MOE) as “Advancement of Environmental Industry Technology Development Program for Environmental Technology (No. 2016000110001)”.

References

1. Noordally E, Richmond JR, Drumm KJ. Catalytic oxidation processes for odour and VOC control. Stud Environ Sci 1994;61:459–467.
2. Volkamer R, Jimenez JL, San Martini F, et al. Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected. Geophys Res Lett 2006;33:L17811.
3. Zou L, Luo Y, Hooper M, Hu E. Removal of VOCs by photocatalysis process using adsorption enhanced TiO2-SiO2 catalyst. Chem Eng Process 2006;45:959–964.
4. Li WB, Wang JX, Gong H. Catalytic combustion of VOCs on non-noble metal catalysts. Catal Today 2009;148:81–87.
5. Mitsuma Y, Ota Y, Hirose T. Performance of thermal swing honeycomb VOC concentrators. J Chem Eng Jpn 1998;31:482–484.
6. Mitsuma Y, Yamauchi H, Hirose T. Analysis of VOC reversing adsorption and desorption characteristics for actual efficiency prediction for ceramic honeycomb adsorbent. J Chem Eng Jpn 1998;31:253–257.
7. Ichiura H, Okamura N, Kitaoka T, Tanaka H. Preparation of zeolite sheet using a papermaking technique. Part II. The strength of zeolite sheet and its hygroscopic characteristics. J Mater Sci 2001;36:4921–4926.
8. Yoo YJ, Kim HS. Adsorption and desorption dynamics of toluene on high silica zeolite honeycomb adsorbent. In : Korean. Soc. Energy Proceedings on Spring Symposium; 2000; p. 307–312.
9. Motsuma Y, Ota Y, Hirose T. Performance of thermal swing honeycomb VOC Concentrators. J Chem Eng Jpn 1998;31:482–484.
10. Chang FT, Lin YC, Bai H, Pei BS. Adsorption and desorption characteristics of semiconductor volatile organic compounds on the thermal swing honeycomb zeolite concentrator. J Air Waste Manage Assoc 2003;53:1384–1390.
11. Yang J, Chen Y, Cao L, Guo Y, Jia J. Development and field-scale optimization of a honeycomb zeolite rotor concentrator/recuperative oxidizer for the abatement of volatile organic carbons from semiconductor industry. Environ Sci Technol 2012;46:441–446.
12. Zhao XS, Ma Q, Lu GQ. VOC Removal: Comparison of MCM-41 with hydrophobic zeolites and activated carbon. Energ Fuel 1998;12:1051–1054.
13. Díaz E, Ordóñez S, Vega A, Coca J. Adsorption characterization of different volatile organic compounds over alumina, zeolites and activated carbon using inverse gas chromatography. J Chromatogr A 2004;1049:139–146.
14. Takeuchi Y, Iwamoto H, Miyata N, Asano S, Harada M. Adsorption of 1-butanol and p-xylene vapor and their mixtures with high silica zeolites. Sep Technol 1995;5:23–34.
15. Lee SW, Kam SK, Lee MG. Comparison of breakthrough characteristics for binary vapors composed of acetone and toluene based on adsorption intensity in activated carbon fixed-bed reactor. J Ind Eng Chem 2007;13:911–916.
16. Monneyron P, Manero MH, Foussard JN. Measurement and modeling of single- and multi-component adsorption equilibria of VOC on high-silica zeolites. Environ Sci Technol 2003;37:2410–2414.
17. Chuang CL, Chiang PC, Chang EE. Modeling VOCs adsorption onto activated carbon. Chemosphere 2003;53:17–27.
18. Bouhamra WA, Elkilani AS, Baker CGJ. Testing adsorbents capacities for indoor volatile organic compounds at optimum operating conditions. WIT Trans Ecol Environ 2006;86:411–420.
19. Yang RT. Gas separation by adsorption processes Boston: Butterworth; 1987. p. 1–48.
20. Brunaure S, Emmett PH. The use of low temperature van def waals adsorption isotherms in determining the surface areas of various adsorbents. J Am Chem Soc 1937;59:2682–2689.
21. Cho MW, An D, Yim B, et al. Toluene adsorption characteristics of zeolite depending on temperature and relative humidity. Odor Indoor Environ 2016;15:368–374.

Article information Continued

Fig. 1

Schematic diagram of the sequential reactor used for adsorption/desorption. VAH-SH and WAH/VAH-CH were filled inside the adsorbent filling module.

Fig. 2

Schematic diagram of the rotary honeycomb adsorption system (a: VAH-SR, b: WAH/VAH-DR) used for VOC removal.

Fig. 3

SEM images of WAH-SH (a1, a2) as fine silica powder-coated honeycomb adsorbent and VAH-SH (b1, b2) as zeolite-coated honeycomb adsorbent.

Fig. 4

a) Toluene adsorption amount as a function of input gas temperature (toluene concentration: 100 ppm; absolute humidity: 28.5 gH2O/kg-dry air; GHSV: 20,000/h; input gas temperature: 40, 50, and 60°C). b) Toluene adsorption amount as a function of input gas absolute humidity (toluene concentration: 100 ppm; absolute humidity: 28.5 and 49.1 gH2O/kg-dry air; GHSV: 20,000/h; input gas temperature: 50°C).

Fig. 5

a) Comparison of the adsorption curves of the single and combined absorbent systems. (toluene concentration: 100 ppm; GHSV: 20,000 /h; absolute humidity: 49.1 gH2O/kg-dry air; input gas temperature: 50°C). b) Comparison of the desorption curves of the single and combined absorbent systems. (inlet temperature: 200°C; gas flow rate: 0.2 NCMM).

Table 1

Physical Properties of ZSM-5, Fine Silica Powder, ZSM-5 Coated Honeycomb, and Silica-Coated Glass Fiber Honeycomb

Sample SBET (m2/g) Vtotal (cm3/g)a Dp (nm)b
Silica powder (SS230) 287.6 1.40 16.8
Parent ZSM-5 zeolite powder 410 0.20 2.9
ZSM-5 zeolite-coated honeycomb 152 0.19 7.0
Silica-coated glass fiber honeycomb 414.5 0.41 3.9
a

Total pore volume evaluated at P/P0 = 0.99.

b

BJH adsorption average pore diameter.

Table 2

Water Adsorption Amount as a Function of Relative Humidity

Honeycomb support Coating material Relative humidity (RH, %) Adsorbent weight (g) Water adsorption amount (mg/g)
Before adsorption After adsorption
Glass fiber Silica powder 15 817 833 20
60 1,060 1,185 118

Table 3

Water Adsorption Amount and Toluene Removal Efficiency of the Single and Dual Honeycomb Rotor System

Rotor Single honeycomb rotor Dual honeycomb rotor


Water content according to the measurement position (gH2O/kg-dry air) Inlet Outlet Difference Inlet Outlet Difference


40.8 34.5 6.3 40.8 29.8 11

Water adsorption amount (m3) 80.7 93.0

Toluene removal efficiency (%) 94.7a 95.7a
88.4b 91.1b
a

Number concentration is 6.6

b

Number concentration is 10